14,995 research outputs found
Carbon deposition in the Bosch process with ruthenium and ruthenium-iron alloy catalysts
The effectiveness of ruthenium and the alloys 50Ru50Fe and 33Ru67Fe as alternatives to iron, nickel, and cobalt catalysts in recovering oxygen from metabolic carbon dioxide was investigated. Carbon deposition boundaries over the unsupported alloys are reported. Experiments were also carried out over 50Ru50Fe and 97Ru3Fe3 catalysts supported on gamma-alumina to determine their performance in the synthesis of low molecular weight olefins. High production of ethylene and propylene would be beneficial for an improvement of an overall Bosch process, as a gas phase containing high olefin content would enhance carbon deposition in a Bosch reactor
Glass bead shot peening retards stress corrosion failure of titanium tanks
Rigidly controlled shot peening retards the incompatibility between titanium alloys and nitrogen tetroxide in rocket-propellant storage tanks. This sets up a residual compressive stress in the surface of a material which reduces tensile stresses in the material fibers, alleviating stress corrosion
Modeling the Void H I Column Density Spectrum
The equivalent width distribution function (EWDF) of \hone absorbers specific
to the void environment has been recently derived (Manning 2002), revealing a
large line density of clouds (dN/dz ~500 per unit z for Log (N_HI)> 12.4). I
show that the void absorbers cannot be diffuse (or so-called filamentary)
clouds, expanding with the Hubble flow, as suggested by N-body/hydro
simulations. Absorbers are here modeled as the baryonic remnants of
sub-galactic perturbations that have expanded away from their dark halos in
response to reionization at z ~ 6.5. A 1-D Lagrangian hydro/gravity code is
used to follow the dynamic evolution and ionization structure of the baryonic
clouds for a range of halo circular velocities. The simulation products at z=0
can be combined according to various models of the halo velocity distribution
function to form a column density spectrum that can be compared with the
observed. I find that such clouds may explain the observed EWDF if the halo
velocity distribution function is as steep as that advanced by Klypin (1999),
and the halo mass distribution is closer to isothermal than to NFW.Comment: 21 pages, 15 figures. Paper in press; ApJ 591, n
Counterions at Charged Cylinders: Criticality and universality beyond mean-field
The counterion-condensation transition at charged cylinders is studied using
Monte-Carlo simulation methods. Employing logarithmically rescaled radial
coordinates, large system sizes are tractable and the critical behavior is
determined by a combined finite-size and finite-ion-number analysis. Critical
counterion localization exponents are introduced and found to be in accord with
mean-field theory both in 2 and 3 dimensions. In 3D the heat capacity shows a
universal jump at the transition, while in 2D, it consists of discrete peaks
where single counterions successively condense.Comment: 4 pages, 3 figures; submitted to Phys. Rev. Lett. (2005
Controlled glass bead peening Patent
Method and apparatus for inducing compressive stresses in pressure vessel to prevent stress corrosio
A ship-based methodology for high precision atmospheric oxygen measurements and its application in the Southern Ocean region
A method for achieving continuous high precision measurements of atmospheric O-2 is presented based on a commercially available fuel-cell instrument, (Sable Systems, Oxzilla FC-II) with a precision of 7 per meg (approximately equivalent to 1.2 ppm) for a 6-min measurement. The Oxzilla was deployed on two voyages in the Western Pacific sector of the Southern Ocean, in February 2003 and in April 2004, making these the second set of continuous O-2 measurements ever made from a ship. The results show significant temporal variation in O-2, in the order of +/- 10 per meg over 6-hourly time intervals, and substantial spatial variation. Data from both voyages show an O-2 maximum centred on 50 degrees S, which is most likely to be the result of biologically driven O-2 outgassing in the region of subtropical convergence around New Zealand, and a decreasing O-2 trend towards Antarctica. O-2 from the ship-based measurements is elevated compared with measurements from the Scripps Institution of Oceanography flask-sampling network, and the O-2 maximum is also not captured in the network observations. This preliminary study shows that ship-based continuous measurements are a valuable addition to current fixed site sampling programmes for the understanding of ocean-atmosphere O-2 exchange processes. [References: 39
Transonic pressure measurements and comparison of theory to experiment for an arrow-wing configuration. Volume 1: Experimental data report, base configuration and effects of wing twist and leading-edge configuration
A wind tunnel test of an arrow-wing-body configuration consisting of flat and twisted wings, as well as a variety of leading- and trailing-edge control surface deflections, was conducted at Mach numbers from 0.4 to 1.1 to provide an experimental pressure data base for comparison with theoretical methods. Theory-to-experiment comparisons of detailed pressure distributions were made using current state-of-the-art attached and separated flow methods. The purpose of these comparisons was to delineate conditions under which these theories are valid for both flat and twisted wings and to explore the use of empirical methods to correct the theoretical methods where theory is deficient
Transonic pressure measurements and comparison of theory to experiment for an arrow-wing configuration. Volume 2: Experimental data report, effects of control surface deflection
For abstract, see N76-11034
Scaling and Universality in the Counterion-Condensation Transition at Charged Cylinders
We address the critical and universal aspects of counterion-condensation
transition at a single charged cylinder in both two and three spatial
dimensions using numerical and analytical methods. By introducing a novel
Monte-Carlo sampling method in logarithmic radial scale, we are able to
numerically simulate the critical limit of infinite system size (corresponding
to infinite-dilution limit) within tractable equilibration times. The critical
exponents are determined for the inverse moments of the counterionic density
profile (which play the role of the order parameters and represent the inverse
localization length of counterions) both within mean-field theory and within
Monte-Carlo simulations. In three dimensions (3D), correlation effects
(neglected within mean-field theory) lead to an excessive accumulation of
counterions near the charged cylinder below the critical temperature
(condensation phase), while surprisingly, the critical region exhibits
universal critical exponents in accord with the mean-field theory. In two
dimensions (2D), we demonstrate, using both numerical and analytical
approaches, that the mean-field theory becomes exact at all temperatures
(Manning parameters), when number of counterions tends to infinity. For finite
particle number, however, the 2D problem displays a series of peculiar singular
points (with diverging heat capacity), which reflect successive de-localization
events of individual counterions from the central cylinder. In both 2D and 3D,
the heat capacity shows a universal jump at the critical point, and the energy
develops a pronounced peak. The asymptotic behavior of the energy peak location
is used to locate the critical temperature, which is also found to be universal
and in accordance with the mean-field prediction.Comment: 31 pages, 16 figure
Exploratory Analysis of Highly Heterogeneous Document Collections
We present an effective multifaceted system for exploratory analysis of
highly heterogeneous document collections. Our system is based on intelligently
tagging individual documents in a purely automated fashion and exploiting these
tags in a powerful faceted browsing framework. Tagging strategies employed
include both unsupervised and supervised approaches based on machine learning
and natural language processing. As one of our key tagging strategies, we
introduce the KERA algorithm (Keyword Extraction for Reports and Articles).
KERA extracts topic-representative terms from individual documents in a purely
unsupervised fashion and is revealed to be significantly more effective than
state-of-the-art methods. Finally, we evaluate our system in its ability to
help users locate documents pertaining to military critical technologies buried
deep in a large heterogeneous sea of information.Comment: 9 pages; KDD 2013: 19th ACM SIGKDD Conference on Knowledge Discovery
and Data Minin
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